That was the first song that came to mind.
Yeah, Like A Rolling Stone is probably, in my not so humble opinion, the single greatest opening track in the history of rock 'n roll.
A few more I forgot about:
Ramblin' Rose - MC5 (Kick Out the Jams)
Astral Weeks - Van Morrison (Astral Weeks)
Tell Me Why - Neil Young (After the Gold Rush)
Watch That Man - David Bowie (Aladdin Sane)
Frownland - Captain Beefheart (Trout Mask Replica)
Born to Lose - Johnny Thunders & the Heartbreakers (LAMF)